03 Mar 2023 09:15:43,579 INFO : Validating data for a ProteomeXchange submission.

03 Mar 2023 09:15:43,581 INFO : =======================================

03 Mar 2023 09:15:43,598 DEBUG: Resetting Job ID: 6c205265-9c13-103b-b327-fea6ddf5f3bc

03 Mar 2023 09:15:43,623 INFO : Starting to run task 'org.labkey.panoramapublic.pipeline.PxDataValidationTask' at location 'webserver'

03 Mar 2023 09:15:43,625 INFO : Validating data for experiment Id: 1584, validation Id: 367

03 Mar 2023 09:15:43,883 INFO : Validating data for 15 Skyline documents in 1 folders

03 Mar 2023 09:15:44,773 INFO : Sample file validation for Skyline document: Method Robustness Assay_3x3x3_Interday.sky.zip

03 Mar 2023 09:15:44,773 INFO :   Found all sample files.

03 Mar 2023 09:15:45,570 INFO : Sample file validation for Skyline document: Milk Allergen Detection from HTST-UHT Beverage Matrix.sky.zip

03 Mar 2023 09:15:45,570 INFO :   Found all sample files.

03 Mar 2023 09:15:45,754 INFO : Sample file validation for Skyline document: Matrix-matched calibration_Cookie Matrix.sky.zip

03 Mar 2023 09:15:45,754 INFO :   Found all sample files.

03 Mar 2023 09:15:46,340 INFO : Sample file validation for Skyline document: Milk Allergen Detection from Cookie-Dough_EggWhiteBG.sky.zip

03 Mar 2023 09:15:46,341 INFO :   Found all sample files.

03 Mar 2023 09:15:46,919 INFO : Sample file validation for Skyline document: Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.sky.zip

03 Mar 2023 09:15:46,920 INFO :   Found all sample files.

03 Mar 2023 09:15:47,119 INFO : Sample file validation for Skyline document: Matrix-matched Calibration_Dough Matrix.sky.zip

03 Mar 2023 09:15:47,119 INFO :   Found all sample files.

03 Mar 2023 09:15:47,452 INFO : Sample file validation for Skyline document: Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.sky.zip

03 Mar 2023 09:15:47,452 INFO :   Found all sample files.

03 Mar 2023 09:15:47,841 INFO : Sample file validation for Skyline document: Matrix-independent Calibration Curve Replicates_EggWhite BG.sky.zip

03 Mar 2023 09:15:47,841 INFO :   Found all sample files.

03 Mar 2023 09:15:48,397 INFO : Sample file validation for Skyline document: Probability of Detection Assay.sky.zip

03 Mar 2023 09:15:48,397 INFO :   Found all sample files.

03 Mar 2023 09:15:48,977 INFO : Sample file validation for Skyline document: QC tracking.sky.zip

03 Mar 2023 09:15:48,977 INFO :   Found all sample files.

03 Mar 2023 09:15:49,201 INFO : Sample file validation for Skyline document: Milk Allergen Detection from Spiked Chocolate Matrix.sky.zip

03 Mar 2023 09:15:49,201 INFO :   Found all sample files.

03 Mar 2023 09:15:49,411 INFO : Sample file validation for Skyline document: Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.sky.zip

03 Mar 2023 09:15:49,411 INFO :   Found all sample files.

03 Mar 2023 09:15:49,493 INFO : Sample file validation for Skyline document: Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.sky.zip

03 Mar 2023 09:15:49,493 INFO :   Found all sample files.

03 Mar 2023 09:15:49,582 INFO : Sample file validation for Skyline document: Impact of matrix in analyte recovery.sky.zip

03 Mar 2023 09:15:49,582 INFO :   Found all sample files.

03 Mar 2023 09:15:49,919 INFO : Sample file validation for Skyline document: Milk Allergen Detection from Casein Chocolate.sky.zip

03 Mar 2023 09:15:49,919 INFO :   Found all sample files.

03 Mar 2023 09:15:50,198 INFO : Modifications validation:

03 Mar 2023 09:15:50,198 INFO : VALID MODIFICATIONS:

03 Mar 2023 09:15:50,198 INFO : 3835: Carbamidomethyl (C): UNIMOD:4 - Carbamidomethyl

03 Mar 2023 09:15:50,198 INFO :     Method Robustness Assay_3x3x3_Interday.sky.zip

03 Mar 2023 09:15:50,199 INFO :     Milk Allergen Detection from Cookie-Dough_EggWhiteBG.sky.zip

03 Mar 2023 09:15:50,199 INFO :     Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.sky.zip

03 Mar 2023 09:15:50,199 INFO :     Milk Allergen Detection from HTST-UHT Beverage Matrix.sky.zip

03 Mar 2023 09:15:50,199 INFO :     Matrix-matched calibration_Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Matrix-independent Calibration Curve Replicates_EggWhite BG.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Probability of Detection Assay.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Matrix-matched Calibration_Dough Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.sky.zip

03 Mar 2023 09:15:50,200 INFO :     QC tracking.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Spiked Chocolate Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Impact of matrix in analyte recovery.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Casein Chocolate.sky.zip

03 Mar 2023 09:15:50,200 INFO : 3836: Oxidation (M): UNIMOD:35 - Oxidation

03 Mar 2023 09:15:50,200 INFO :     Method Robustness Assay_3x3x3_Interday.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Cookie-Dough_EggWhiteBG.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from HTST-UHT Beverage Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Matrix-matched calibration_Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Matrix-independent Calibration Curve Replicates_EggWhite BG.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Probability of Detection Assay.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Matrix-matched Calibration_Dough Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.sky.zip

03 Mar 2023 09:15:50,200 INFO :     QC tracking.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Spiked Chocolate Matrix.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Impact of matrix in analyte recovery.sky.zip

03 Mar 2023 09:15:50,200 INFO :     Milk Allergen Detection from Casein Chocolate.sky.zip

03 Mar 2023 09:15:50,200 INFO : 3837: Label:13C(6)15N(2) (C-term K): 

03 Mar 2023 09:15:50,200 INFO :     Method Robustness Assay_3x3x3_Interday.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Cookie-Dough_EggWhiteBG.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from HTST-UHT Beverage Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Matrix-matched calibration_Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Matrix-independent Calibration Curve Replicates_EggWhite BG.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Probability of Detection Assay.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Matrix-matched Calibration_Dough Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.sky.zip

03 Mar 2023 09:15:50,201 INFO :     QC tracking.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Spiked Chocolate Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Impact of matrix in analyte recovery.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Casein Chocolate.sky.zip

03 Mar 2023 09:15:50,201 INFO : 3838: Label:13C(6)15N(4) (C-term R): 

03 Mar 2023 09:15:50,201 INFO :     Method Robustness Assay_3x3x3_Interday.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Cookie-Dough_EggWhiteBG.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from HTST-UHT Beverage Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Matrix-matched calibration_Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Matrix-independent Calibration Curve Replicates_EggWhite BG.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Probability of Detection Assay.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Matrix-matched Calibration_Dough Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.sky.zip

03 Mar 2023 09:15:50,201 INFO :     QC tracking.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Milk Allergen Detection from Spiked Chocolate Matrix.sky.zip

03 Mar 2023 09:15:50,201 INFO :     Impact of matrix in analyte recovery.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Casein Chocolate.sky.zip

03 Mar 2023 09:15:50,202 INFO : 3839: Label: 13C(6)15N(1) (C-term I): 

03 Mar 2023 09:15:50,202 INFO :     Method Robustness Assay_3x3x3_Interday.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Cookie-Dough_EggWhiteBG.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from HTST-UHT Beverage Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Matrix-matched calibration_Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Matrix-independent Calibration Curve Replicates_EggWhite BG.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Probability of Detection Assay.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Matrix-matched Calibration_Dough Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.sky.zip

03 Mar 2023 09:15:50,202 INFO :     QC tracking.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Spiked Chocolate Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Impact of matrix in analyte recovery.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Casein Chocolate.sky.zip

03 Mar 2023 09:15:50,202 INFO : 3840: Label:13C(6)15N(2) (C-term V): 

03 Mar 2023 09:15:50,202 INFO :     Method Robustness Assay_3x3x3_Interday.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Cookie-Dough_EggWhiteBG.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from HTST-UHT Beverage Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Matrix-matched calibration_Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Matrix-independent Calibration Curve Replicates_EggWhite BG.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Probability of Detection Assay.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Matrix-matched Calibration_Dough Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.sky.zip

03 Mar 2023 09:15:50,202 INFO :     Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.sky.zip

03 Mar 2023 09:15:50,202 INFO :     QC tracking.sky.zip

03 Mar 2023 09:15:50,203 INFO :     Milk Allergen Detection from Spiked Chocolate Matrix.sky.zip

03 Mar 2023 09:15:50,203 INFO :     Impact of matrix in analyte recovery.sky.zip

03 Mar 2023 09:15:50,203 INFO :     Milk Allergen Detection from Casein Chocolate.sky.zip

03 Mar 2023 09:15:50,203 INFO : INVALID MODIFICATIONS (No Unimod ID):

03 Mar 2023 09:15:50,205 INFO : Validating spectral library: new test.blib

03 Mar 2023 09:15:50,251 INFO : 'New test' (new test.blib) library in 1 Skyline documents was built with 2 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,252 INFO : Validating spectral library: QC tracking.blib

03 Mar 2023 09:15:50,305 INFO : 'QC tracking' (QC tracking.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,306 INFO : Validating spectral library: Milk_library_1.blib

03 Mar 2023 09:15:50,656 INFO : 'Milk library 1' (Milk_library_1.blib) library in 14 Skyline documents was built with 2 raw files; 1 peptide Id files. Status: VALID

03 Mar 2023 09:15:50,657 INFO : Validating spectral library: Matrix-independent Calibration Curve Replicates_EggWhite BG.blib

03 Mar 2023 09:15:50,706 INFO : 'Matrix-independent Calibration Curve Replicates_EggWhite BG' (Matrix-independent Calibration Curve Replicates_EggWhite BG.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,708 INFO : Validating spectral library: Milk Allergen Detection from Spiked Chocolate Matrix.blib

03 Mar 2023 09:15:50,754 INFO : 'Milk Allergen Detection from Spiked Chocolate Matrix' (Milk Allergen Detection from Spiked Chocolate Matrix.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,755 INFO : Validating spectral library: Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.blib

03 Mar 2023 09:15:50,807 INFO : 'Milk Allergen Detection from Spiked vs Incurred Cookie Matrix' (Milk Allergen Detection from Spiked vs Incurred Cookie Matrix.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,808 INFO : Validating spectral library: Matrix-matched calibration_Cookie Matrix.blib

03 Mar 2023 09:15:50,859 INFO : 'Matrix-matched calibration_Cookie Matrix' (Matrix-matched calibration_Cookie Matrix.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,861 INFO : Validating spectral library: Probability of Detection Assay.blib

03 Mar 2023 09:15:50,913 INFO : 'Probability of Detection Assay' (Probability of Detection Assay.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,915 INFO : Validating spectral library: Milk Allergen Detection from Casein Chocolate.blib

03 Mar 2023 09:15:50,961 INFO : 'Milk Allergen Detection from Casein Chocolate' (Milk Allergen Detection from Casein Chocolate.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:50,963 INFO : Validating spectral library: Milk Allergen Detection from Cookie-Dough_EggWhiteBG.blib

03 Mar 2023 09:15:51,015 INFO : 'Milk Allergen Detection from Cookie-Dough_EggWhiteBG' (Milk Allergen Detection from Cookie-Dough_EggWhiteBG.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,016 INFO : Validating spectral library: Milk Allergen Detection from HTST-UHT Beverage Matrix.blib

03 Mar 2023 09:15:51,067 INFO : 'Milk Allergen Detection from HTST-UHT Beverage Matrix' (Milk Allergen Detection from HTST-UHT Beverage Matrix.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,069 INFO : Validating spectral library: Matrix-matched Calibration_Dough Matrix.blib

03 Mar 2023 09:15:51,160 INFO : 'Matrix-matched Calibration_Dough Matrix' (Matrix-matched Calibration_Dough Matrix.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,162 INFO : Validating spectral library: Milk_library_3.blib

03 Mar 2023 09:15:51,600 INFO : 'Milk library 3' (Milk_library_3.blib) library in 14 Skyline documents was built with 6 raw files; 1 peptide Id files. Status: VALID

03 Mar 2023 09:15:51,601 INFO : Validating spectral library: 20181103_BR_NFDM_10ppm_cookie-dough_desalting column tests.blib

03 Mar 2023 09:15:51,641 INFO : '20181103_BR_NFDM_10ppm_cookie-dough_desalting column tests' (20181103_BR_NFDM_10ppm_cookie-dough_desalting column tests.blib) library in 1 Skyline documents was built with 1 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,643 INFO : Validating spectral library: Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.blib

03 Mar 2023 09:15:51,695 INFO : 'Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG' (Milk Allergen Detection from Cookie-Dough_PorcineGelatinBG.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,696 INFO : Validating spectral library: Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.blib

03 Mar 2023 09:15:51,744 INFO : 'Milk Allergen Detection from Dough Matrix by Standard Addition Calibration' (Milk Allergen Detection from Dough Matrix by Standard Addition Calibration.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,745 INFO : Validating spectral library: Method Robustness Assay_3x3x3_Interday.blib

03 Mar 2023 09:15:51,792 INFO : 'Method Robustness Assay_3x3x3_Interday' (Method Robustness Assay_3x3x3_Interday.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,793 INFO : Validating spectral library: Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.blib

03 Mar 2023 09:15:51,844 INFO : 'Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material' (Milk Allergen Detection from Incurred Gluten-free Cookie Reference Material.blib) library in 1 Skyline documents was built with 3 raw files; 0 peptide Id files. Status: Missing peptide ID file names in the .blib file.

03 Mar 2023 09:15:51,844 INFO : Spectral library validation complete.

03 Mar 2023 09:15:51,845 INFO : Data validation is complete. Status is IncompleteMetadata

03 Mar 2023 09:15:51,845 INFO : Successfully completed task 'org.labkey.panoramapublic.pipeline.PxDataValidationTask'